WebZeitschrift für anorganische und allgemeine Chemie. Volume 429, Issue 1 p. 231-236 p. 231-236 Tetracyanoquinodimethane and Derivatives. 7,7′,8,8′-Tetracyanoquinodimethane (TCNQ) and its derivatives (Scheme 1 B and C) are known for their strong electron-accepting properties. The charge transfer salt from TCNQ and tetrathiofulvalene has been the first purely organic conductor.
ECS Meeting Abstracts, Volume MA2024-02, Number 40, July …
WebPolarized single crystal reflectance spectra of the linear metal–chain complexes Pt(bqd)2, α‐Pd(bqd)2, β‐Pd(bqd)2, Pd(bqd)2I0.55, Ni(bqd)2, and Ni(bqd)2I0.5 (bqd−=ion of 1,2‐benzoquinonedioxime, bqdH) have been recorded at room temperature. Well‐defined sharp absorption bands polarized parallel to the metal atom chains are observed in the … WebOur continued study of derivatives of the 7,7,8,8-tetracyanoquinodimethan anion–radical (TCNQ−•) has shown that the simple N-methylphenazinium salt (IIa) exhibits a volume electrical resistivity of 7 × 10−3 Ω cm and thus is the most highly electrically conductive organic compound known. In contrast, the N-ethyl analogue has a resistivity of 109 Ω … probiotics through food
Ein donor-acceptor- [2.2]Paracyclophan mit …
WebTetracyanochinodimethan (TCNQ) ist eine organische Substanz, welche mit 1,4-Benzochinon verwandt und ein organisches Halbleitermaterial ist. Das Nitril stellt einen … Webbenzochinon (TCQ) und Tetracyanochinodimethan (TCNQ) vielfältige Folgechemie. Sowohl die Bildung von polymeren Koordinationsverbindungen mit verbrückenden Silberhalogenid-Clustern wie {[1][Ag 5Br4I3]}n als auch Reaktionen unter Auflösung der Kette und Bildung von Donor-Akzeptor-Paaren [1][2DDQ] wird beobachtet. Webcobalt atoms advances its physical properties by accommodating Tetracyanochinodimethan (TCNQ), an acceptor molecule. Strong intermolecular charge transfer narrows the optical band gap down to 1.5 eV of divalent TCNQ and enhances the electrical conduction, which allows the MOF to be utilized for resistive gas- and photo … regency at dell ranch